OH Bbi
3,4-Ditosyl, di-Me acetal 2,5-Anhydro-3,4-di-O-tosyl-D-lyxose dimethyl acetal Mp 139-140 . a r gt 63.5 CHCl3 . 3,4-Ditosyl, di-Me acetal 2,5-Anhydro-3,4-di-O-tosyl-L-lyxose dimethyl acetal Mp 139-140 . a D -58.5 c, 1.3 in CHCl3 . Defaye, J. et al., Carbohydr. Res., 1971, 20, 305 1,6-Anhydro-4-O- a-D-glucopyranosyl - -D-glucopyranose. Maltosan 6983-27-3
O Ynm
Mp 82-83 . a D3 40.5 c, 1.0 in CHCl3 . 2,4-Dinitrophenylhydrazone Mp 180 . a D' 13.1 c, 0.4 in CHCl3 . 4-Ac C14H16O5 264.277 a D3 26.6 c, 1.0 in CHCl3 . Mp 95-96 . a D2 -23.1 c, 1.0 in CHCl3 . Collins, P.M. et al., Carbohydr. Res., 1974, 32, 203 Fischer, J.-C. et al., Can. J. Chem., 1977, 55, 4078
Dglycero Ltalo Heptonic acid dgulo Hexonolactone
D-glycero-l-talo -Heptonic acid, H-29 D-glycero-D-galacto -Heptono-1,4-lactone, H-23 D-glycero-D-gulo -Heptono-1,4-lactone, H-25 D-glycero-d-ido -Heptono-1,4-lactone, H-26 D-glycero-L-manno -Heptono-1,4-lactone, H-27 D-glycero-d-talo -Heptono-1,4-lactone, H-28 D-glycero- l-talo -Heptono-1,4-lactone, H-29 a-D-gluco -2-Heptulopyranosonic acid, H-64 Heptyl H-65 3- O -Heptyl-1,2- O -isopropylidene-a-d-glucofuranose, S-28 S-28 Herpid, D-278 Herplex, D-278 Hetangmycin, R-143 Hexa-O...
A Uxw
15218-38-9 Amino sugar antibiotic. Produced by several Streptomyces spp. Primarily active against gram-positive bacteria. Sol. H2O fairly sol. MeOH, EtOH poorly sol. butanol, hexane. Mp 126-130 dec. a D4 100 3 min. - gt 73.5 20 hr. . LD50 mus, ipr 1600 mg kg LD50 mus, ivn 1250 mg kg. LZ5655000 1-Deoxy See H-175 Mp 122-124 . a D0 -72.1 c, 0.3 in H2O . Inouye, S. et al., J. Antibiot., 1966, 19, 288 struct, nmr Saeki, H. et al., Chem. Pharm. Bull., 1968, 16, 962 synth Inouye, S. et al.,...
OH Oyi
Metab. of Pseudomonas spp. grown on d-glucose and of many other bacteria. Isol. as a trihydrated Ca salt. a D -99.6. Cryst. H2O . Mp 177-179 . a D5 61.3 c, 0.2 in DMF . Quinoxaline deriv. Cryst. H2O . Mp 199-200 . a D0 -87.5 c, 2.0 in M NaOH . Me ester Methyl d-arabino-hex-2-uloso-nate Mp 173 dec. a D0 -82.08 mutarotates . Me ester, phenylhydrazone Mp 163 . a D -124.1. Me ester, 3,4,5,6-tetra-Ac Methyl C15H20O 376.316 Bp0.3 199-203 . a D8 -38.8 CHCl3 . Et ester Ethyl d-arabino-hex-2-ulosonate...
OH OH Qry
C9H12FN3O5 261.209 Cryst. EtOH . Mp 193-193.5 2'-Deoxy 2' -Deoxy-5-fluorocytidine, 9CI, 8CI 10356-76-0 C9H12FN3O4 245.21 Cryst. EtOH . Mp 195-196.5 . a D6 66 c, 2.5 in H2O . LD5o rat, ipr 2000 mg kg. Exp. reprod. and teratogenic effects. HA3850000 3'-Deoxy 3'-Deoxy-5-fluorocytidine. 5-Fluoro-3'-deoxycytidine C9H12FN3O4 245.21 Cryst. EtOH . Mp 194-195 . 1max 238 e 7600 289 7700 H2O . Aldrich Library of FT-NMR Spectra, 3, 383C nmr Wempen, I. et al., J.A.C.S., 1961, 83, 4755 2' -deoxy Utz, J.P. et...
A Drj
C54H90O16 995.295 Polyether antibiotic. Isol. from Strepto-myces hygroscopicus. Antibacterial agent. Cryst. powder. Related to Le-noremycin. 1max 235 MeOH Berdy . Tsuji, N. et al., J. Antibiot., 1980, 33, 94 isol, struct, ir, pmr, cmr C37H50N6O15 818.833 Nucleoside antibiotic. Isol. from Streptomyces capreolus. Active against grampositive bacteria. Cryst. Sol. MeOH, CHCl3 poorly sol. H2O, hexane, CCl4, Et2O. Mp 135-137 . a D5 -114 c, 1 in MeOH . pKa 11.4 66 DMF aq. . 1max 268 e 44600 325 e...
A Wsb
Cryst. 2-propanol . Mp 115-116 . a D7 -21.9 c, 2.5 in H2O . 6-O-Dodecanoyl Sorbitan monolaurate, BAN, USAN. Sorbitan laurate, INN. Sorbester P12. Span 20. E493 1338-39-2 C18H34O6 346.463 Nonionic surface active agent. Used as a 0.1 soln. in toluene for extraction-photometric detn. of SO4e 1max 600 nm, e 15000, toluene . Sorbitan esters used as emulsifying agents in pharmaceutical and cosmetic preparations. Used in foods, e.g. as emulsifier. Eye irritant. LD50 rat, orl 33600 mg kg. WG2920000...
HO OH Jid
Tribenzoyl 2,3,4-Tri-O-benzoyl-a-d-ribo-pyranosyl chloride 13035-47-7 C26H21ClO7 480.9 Needles CHCl3 Et2O . Mp 203-204 . a D0 60 c, 0.9 in CHCl3 . Tri-Ac 2,3,4-Tri-O-acetyl- -d-ribopyra-nosyl chloride 4049-36-9 C11H15ClO7 294.688 Cryst. Et2O . Mp 95 . a D2 -169.6 CHCl3 . Tribenzoyl 2,3,4-Tri-O-benzoyl- -d-ribo-pyranosyl chloride 13035-43-3 C26H21ClO7 480.9 Prisms CH2Cl2 Et2O . Mp 162-163 . a D0 -147 CHCl3 . Tris chlorosulfate 18417-46-4 Cryst. EtOH aq. . Mp 132 . a D -108 c, 0.8 in CHCl3 ....
OH Rds
C10H14N2O6 258.23Log P -2.33 calc . Spongothymidine. Ara-T Isol. from Caribbean sponge, Cryptotethia crypta. Antiviral agent. HIV reverse transcriptase HIV-rt inhibitor. Mp 194-195 Mp 242 . a D8 90 c, 0.8 in Py . Low acute toxicity. 1max 267 e pH 12 Derep . 1max 267 e 9600 pH 7.2 Derep . 1max 269 e 9250 H2o Berdy . Bergmann, W. et al., J.O.C., 1955, 20, 15011507 isol, struct Fr. Pat., 1965, 1 396 003, Upjohn CA, 63, 13392d synth Tougard, P. et al., Acta Cryst. B, 1973, 29, 22272232 cryst struct...
C Gfm
A linear polymer of 2-Acetamido-2-deox-yglucose, A-8. Minimum formula given. Occurs in shells of crustacea, most fungi, mycelial yeast, green algae and some brown and red algae. Antihae-morrhagic. Used as a wound healant. a D0 -14 - gt 56 HCl . The fully N -deacetylated prod. is called Chitan. LD50 rat, ivn 50 mg kg. FM6125000 Partially deacylated deriv. See Chitosan in The Combined Chemical Dictionary. 39280-86-9, 87582-10-3, 88650-88-8 Foster, A.B. et al., Adv. Carbohydr Chem., 1960, 15, 371...
HO Uod
C59H109N6O19P 1237.513 Used in antibiotic preparations. Antineoplastic agent. U.S. Pat., 1983, 4 414 204 CA, 100, 161784g synth Murray, J.L. et al., J. Clin. Oncol., 1989, 7, 1915-1925 1991, 9, 259-267 1992, 10, 1310-1316 pharmacol Vail, D.M. et al., Clin. Cancer Res., 1995, 1, 1165-1170 1595-1601 1999, 5, 4249-4258 pharmacol 9CI C9H22NO 8 176.278 Present in Amanita muscaria. Mp 129131 dec. as tetrachloroaurate . a D 20.5 tetrachloroaurate . Stereochem. of the nat. prod. could not be confirmed....
OH OH Mvb
Tetrakis 3-pyridinecarbonyl , Me ester Nicofurate, INN Arteriolase. GN 3. Tetnicoran 4397-91-5 C35H28N4O11 680.626 No longer marketed Vasodilator, antilipidaemic agent. Cryst. MeOH Et2O . Mp 122.5-124 . Log P 2.56 uncertain value calc . Fr. Pat., 1965, 1 404 748, Fujisawa Pharm CA, 64, 712d synth Martindale, The Extra Pharmacopoeia, 28th 29th edn., Pharmaceutical Press, 1982, 13010 4- Methylthio -3-butenyl glu- M-289 cosinolate date , 9CI. Glucoraphasatin. Glucodehy- S-Oxide 4- Methylsulfinyl...
Indexes
1 A Name Index which lists every compound name and synonym in the Dictionary, and 2 A Type of Compound index listing all compounds given in the Dictionary. The indexes refer to the entry number. In the Name Index an entry number preceded by the word 'see' means that the name listed is a synonym to an entry name, and appearance of the term 'in' means that the name listed is the name of a derivative embedded within the entry. Searches on all text and numerical indexes, as well as structure and...
Aminodarabinofuranosyl
Allyl 3,4- O-isopropylidene-a-d-glucopyranoside, A-94 Allyl 3,4- O -isopropylidene-2- O -tosyl- -d-arabinopyranoside, A-90 Allyl 2-O -methyl-a-l-fucopyranoside, A-92 Allyl 4-O -methyl-a-l-rhamnopyranoside, A-95 Allyl 2,3,4,6-tetra-O -acetyl-a-d-glucopyranoside, A-94 Allyl 2,3,4,6-tetra-O -acetyl- -d-glucopyranoside, A-94 Allyl 2,3,4,6-tetra-O -benzoyl-a-d-mannopyranoside, P-96 Allyl 2-O -tosyl- -d-arabinopyranoside, A-90 Allyl 3,4,6-tri-O-acetyl-a-d-glucopyranoside, A-94 Allyl...
OH Bml
Constit. of Aculeximycin isol. from the culture broth of Streptosporangium albi- N-Ac 122037-04-1 C20H35NO12 481.496 Amorph. powder. Mp 162-166 . a D4 16.5 c, 1.0 in MeOH . Hepta-Ac 122037-02-9 C32H47NO18 733.719 Amorph. powder. Mp 123-127 . a D4 51.3 c, 0.1 in MeOH . Murata, H. et al., J. Antibiot., 1989, 42, 691 701 isol, synth, pmr, cmr, ms, hplc hydroxide inner salt, 9CI. S-Adenosylmethionine. Active methionine 2613-02-7
Pseudoadgalactopyranose alRhamnopyranosyl
Pseudo-a-d-galactopyranose, H-158 Pseudo-a-dl-galactopyranose, H-158 Pseudo- -dl-galactopyranose, H-158 Pseudo-a-l-glucopyranose, H-158 Pseudo- -d-glucopyranose, H-158 Pseudo- -l-glucopyranose, H-158 Pseudo-a-d-glucopyranose, H-158 Pseudo-a-dl-glucopyranose, H-158 Pseudo- -dl-glucopyranose, H-158 Pseudo- -d-gulopyranose, H-158 Pseudo-a-l-idopyranose, H-158 Pseudo-a-dl-idopyranose, H-158 Pseudolactobiuronic acid, G-148 Pseudomaltobiuronic acid, G-413 Pseudo- -l-mannopyranose, H-158 Pseudo-...
Glycosyl halides and other halogenosugars
fluoride, A-224 6-Acetamido-6-deoxy-a-d-glucopyranosyl fluoride, A-225 2-Acetamido-2-deoxy-3,4,6-tri-O -acetylglucopyranosyl chloride a-d-form, A-9 2-Acetamido-2-deoxy-3,4,6-tri-O -acetylglucopyranosyl chloride, A-9 2-Acetamido-3,4,6-tri-O -acetyl-2-deoxy-a-d-galactopyranosyl chloride, A-192 2-Acetamido-3,4,6-tri-O -acetyl-2-deoxy-a-d-glucopyranosyl bromide, A-223 2-Acetamido-3,4,5-tri-O -acetyl- -d-glucopyranosyl fluoride, A-224 2-O-Acetyl-3,6-anhydro-5-O -benzoyl- -l-idofuranosyl fluoride,...
O Yra
1,2-Di-Ac 58645-41-3 C12H18O7 274.27 Mp 118-119 . a D -49 c, 1.0inCHCl3 . 2-Me C9H16O5 204.222 Mp 115-117 . Mp 82-85 78 . a D -156 0 -111 24 hr. c, 1.1 in H2O . 2-Benzoyl C15H18O6 294.304 Mp 120-121 . a D -145 MeOH . 1,2-O-Isopropylidene 20881-03-2 C H18O5 230.26 Mp 40-41 . a D -4 H2O . -l-Pyranose- orm 40031-36-5 Mp 80 . a D 128.8 H2O . 1,2-O-Isopropylidene 27820-98-0 C H18O5 230.26 Mp 41-43 . a D 5.4 H2O . Me glycoside See Methyl 3,4-O-isopro- pylidenearabinopyranoside, M-197 Stanek, J. et...
CHO Hie
Non-reducing trisaccharide. Formed by the transglucosylation reaction of brewers yeast a-glucosidase. a D 96 c, 0.5 in H2O . Matsusaka, K. et al., Agric. Biol. Chem., 1975, 39, 725 a-d-Glucopyranosyl- 1 -d-glucopyranosyl- 1 0 9CI Amorph. a D3 141.5 c, 1.1 in H2O . Benzyl glycoside, 2' ,2'' ,3,3' ,3'' ,4'',6',6''-octabenzyl 132627-99-7 C80H84O15 1285.535 Syrup. a D5 33 c, 1.5 in CHCl3 . Chirva, V.Y. et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1968, 2541 Bull. Acad. Sci. USSR, Div. Chem. Sci. Engl....
HO Lew
C18H22I3N3O8 789.101 Radiopaque substance contrast agent used in spinal cord and CNS radiology. Cryst. 2-propanol . Mp 230 dec. ajg1 18 c, 0.13 in 0.1N HCl . Human systemic effects when used ther-apeutically. LD50 rat, scu 17 mg kg. Exp. reprod. and teratogenic effects. LZ6650000 Aldrich Library of FT-IR Spectra, 1st edn., 1985, 2, 421B ir Ger. Pat., 1971, 2 031 724 CA, 74, 99662e synth Mathias, A.P. et al., FEBS Lett., 1973, 33, 18 Rickwood, D. et al., FEBS Lett., 1975, 50, 102 rev Hol, L. et...
HO O OH Bcw
Reducing disaccharide. Constit. of the repeating unit of the capsular antigen of Klebsiella spp. and of the O -antigens of Pseudomonas aeruginosa immunotype 5, Shigella flexneri, Shigella dysenteriae type 1 and Klebsiella 07. Cryst. MeOH CHCl3 . Mp 141-142 . a D -41 c, 0.9 in H2O 21 . a-Pyranose-form 22393-20-0 Hexa-Ac 68355-16-8 C24H34O15 562.524 Solid EtOH . Mp 78-80.5 75-76 . a D -43.6 c, 0.51 in CHCl3 . Me glycoside 71348-37-3 C13H24O9 324.327 Cryst. MeOH diisopropyl ether . Mp 181-183.5 ....
HO OH Gwj
Extracted from the stem bark of Mezzettia leptopoda Annonaceae . Cytotoxic agent. Gum. a D -63 c, 0.54 in CHCl3 . 134857-00-4 C46H76O22 981.093 From Mezzettia leptopoda. Gum. a D -35 c, 0.23 in CHCl3 . 3' ' '-Ac Mezzettiaside 5 134856-99-8 C46H76O22 981.093 From Mezzettia leptopoda. Gum. a D -57 c, 0.37 in CHCl3 . 3' ' -Deglycosyl Mezzettiaside 4 135091-79-1 C38H64O17 792.913 From Mezzettia leptopoda. Exhibits weak cytotoxicity. Gum. a D -54 c, 0.46 in CHCl3 . 3' ' -Deglycosyl, 2' '-Ac...
S Wds
N-Octadecanoyl N-Octadecanoylphyto-sphingosine 34354-88-6 Mp 99-100 . N-Octadecanoyl, 1-O- -D-galactopyrano-side 139973-77-6 C42H83NO9 746.119 Cryst. CHCl3 MeOH . Mp 197-198 . a D -1.4 c, 3 in Py . a D0 10.4 c, 3 in EtOH CHCl3 . N-Tetracosanoyl 34437-74-6 C42H85NO4 668.138 Constit. of various marine sources and Physalis philadelphica. Amorph. powder. Mp 114-116 . a D 19.5 c, 0.2 in Py . N- 2R-Hydroxyoctadecanoyl 6591397-5 C36H73NO5 599.976 Constit. of the coral Sinularia leptoclados. Powder as...
Adonitol Allyl O isopropylidene
Adonitol, R-94 Adonose, P-47 eADP, R-110 ADP, A-33 ADPG, A-36 ADPR, A-37 Adriacin, A-58 Adriamycin, A-58 Adriamycinol, A-58 Adriamycinone, A-58 Adriblastin, A-58 AE-cellulose, C-48 Aedurid, E-2 Aerosporin, S-86 AF, A-879 Afragilimycin A, S-82 AG 12, D-771 2AG, A-277 Agar, A-59 Agar-agar, A-59 Agarobiose, A-60 Agarose 6-aminohexyl carbamimidate, A-61 1,2-Aldodiose bis phenylhydrazones , H-90 a-d-Allopyranosyl a-d-allopyranoside, A-80 a-d-Allopyranosyl p-d-fructofuranoside, A-83 a-d-Allopyranosyl...
CHNOP Qka
Rammler, D.H. et al., J.A.C.S., 1962, 84, 3112-3122 synth Griffin, B.E. et al., Tetrahedron, 1967, 24, 639-662 synth Ts'o, P.O.P. et al., Biochemistry, 1969, 8, 997-1029 pmr Warshaw, M.M. et al., Biopolymers, 1970, 9, 1079-1103 cd Ganglioside GA3. Lactosylceramide. 1-O- C54H103NO13 974.407 Isol. from human epidermoid cells. Major neutrophil glycolipid serving as a differentiation marker. FK1000000 71965-57-6 Rapport, M.M. et al., Cancer Philadelphia , 1959, 12, 438 isol Rapport, M.M. et al., J....
Chnop 1
Isol. from yeast ribonucleic acid. Also Mp 205-215 187 dec. pKa1 0.89 pKa2 3.81 pKa3 6.17 25 . Acridine salt Mp 215 dec. Dibrucine salt Mp 165-175 . 3' Adenophostin A 149091-92-9 C 6H26N5O18P3 669.325 Prod. by Penicillium brevicompactum. Calcium channel activator. Activates in-ositol triphosphate Ins 1,4,5 P3 receptor. Sol. H2O, DMSO fairly sol. MeOH, EtOH poorly sol. Me2CO, CHCl3, EtOAc. a D5 28.6 c, 0.7 in H2O . Adenylyl- 2' 05 -adenosine, 9CI - Adenylyl- 5' 0 2 -adenylyl-
Alicyclic Diamines The Geometric Isomers Of Bis 4-aminocyclohexyl Methane 1951
a,a,a-Trifluorothymidine, D-381 Trifluridine, D-381 Triformin, G-552 A-86 1,3,6-Tri-O-galloyl- -d-allopyranose, A-86 1,2 ,5-Tri-O-galloylhamamelofuranose, H-181 2,2 ,5-Tri-O-galloylhamamelofuranose, H-181 2 ,3,5-Tri- O -galloylhamamelofuranose, H-181 H-181 1,3,5-Tri-O-galloyl-proZo-quercitol, Q-6 1,4,5-Tri- O -galloyl-proZo -quercitol, Q-6 2,4,5-Tri-O-galloyl-proZo-quercitol, Q-6 3,4,5-Tri-O-galloyl-proZo-quercitol, Q-6 1.3.4-Tri-O-galloylquinic acid, Q-10 3.4.5-Tri-O-galloylquinic acid, Q-10...
Aminodeoxydglucopyranosyl
C-199 p-Aminobenzyl 1-thio-p-d-cellobioside, T-60 A-445 5-Amino-3- O -benzyl-5-deoxy-1,2- O -isopropylidene-a-d-xylofuranose, A-358 5-Amino-3-O-benzyl-5,6-dideoxy-1,2-O -isopropylidene-p-l-talofuranose, A-418 T-133 A-469 M-324 hydroxide C-77 9-Amino-4-demethoxy-9-deoxy-7- O - 2-deoxy- p-d-erythro -pentopyranosyl - daunomycinone, A-474 2 -Amino-2 -deoxyadenosine, A-328 3'-Amino-3'-deoxyadenosine, A-154 2-Amino-2-deoxyallitol, A-155 6-Amino-6-deoxyallose, A-159 3-Amino-3-deoxyalluronic acid,...
A A 1
Goeke, K. et al., J. Antibiot., 1996, 49, 661-663 664 7-phosphate Mahmud, T. et al., Chem. Rev., 2001, 300-301 rev, biosynth Bowers, S.G. et al., Carbohydr. Res., 2002, 337, 297-304 biosynth, bibl Perion, R. et al., Carbohydr. Res., 2003, 338, 2779-2792 synth Carrisyn. Polymannoacetate 110042-95-0 Long chain polymer consisting of linear 1 - 4 -D-mannopyranosyl units, randomly acetylated 0.8 Ac per monomer MW gt 10000 Dalton. Constit. of leaf juice of Aloe barbadensis and Aloe arborescens...
CHNO Oge
Part of the Forssman antigen. a D 134 Paulsen, H. et al., Carbohydr. Res., 1982, 100, 143 synth Poppe, L. et al., Biochem. Biophys. Res. Commun., 1989, 159, 618 1991, 174, 1169 pmr, conformn Nilsson, U. et al., Carbohydr. Res., 1994, 252, 137 synth Gronberg, G. et al., Carbohydr. Res., 1994, 257, 35 conformn Astromicin, INN. Abbott 44747. KW1070. XK 70-1. Antibiotic KW 1070 55779-06-1 C17H35N5O6 405.493 Aminoglycoside antibiotic. Isol. from Micromonospora spp. Antibacterial agent. Launched...
CHNO Esf
Sol. H2O fairly sol. MeOH poorly sol. Polymycin B. NT 1009. Antibiotic NT 1009. Racemomycin E. A 53930C. Antibiotic A 53930C 3484-68-2 C43H82N16O12 1015.221 Sol. H2O fairly sol. MeOH poorly sol. butanol, hexane. Mp 61-65 . a D -12.8 c, 0.5 in H2O . LD50 mus, ivn 7.5 mg kg. NJ5830700 Racemomycin D. OP 2D. Antibiotic OP 2D 3776-36-1 C37H70N14O 887.047 Prod. by Streptomyces lavendulae. Shows activity against insects, bacteria, viruses and fungi. Sol. H2O fairly sol. MeOH poorly sol. butanol,...
R R Waw
Aminoglycoside antibiotic complex. Isol. from Pseudomonas fluorescens and Streptoverticillium netropsis. Active against gram-positive and -negative bacteria. Antibiotic P 2563I. Antibiotic P 2563P. Antibiotic BN 186A. Antibiotic BU2183A. Antibiotic GIA1. BN 186A. BU 2183A. GIA1. P 2563I. P 2563P 60534-70-5 C15H31N3O9 397.425 a D 87.1 c, 1 in H2O . Prisms 2H2O. Mp 105-115 . a D5 60.3 c, 1 in H2O . Carbonate 2 1 a D 78.5 c, 1 in H2O . Sorbistin A2 BU 2183A2. Antibiotic BU 2183A2 - LD50 mus, ivn...
Chemical Properties Of Glycerol Triformate
Natural glycerophosphoric acid obt. from biol. sources is a mixt. of ca. 25 Glycerol 1-monophosphate, G-550 and 75 Glycerol 2-monophosphate. a Dca. -0.5 . Synthetic glyceropho-sphoric acid prepd. by phosphorylation of glycerol has varying isomeric composition. Syrup. pKa2 6 25 , 1.0M KCl . Hygroscopic, dec. on dist. Mono-Na safcCariostatic used in mouthwashes. Ca sa t 55701-23-0 Cryst. 1H2O. Cryst. EtOH petrol . Mp 137-137.5 . 927-20-8, 1319-69-3, 1319-70-6, 1320-46-3, Baer, G. et al., J. Biol....
Acetamidodideoxyd
2-Acetamido-2,6-dideoxy-d-galactose, A-375 2-Acetamido-2,6-dideoxy-d-glucose, A-380 2-Acetamido-2,3-dideoxy-d-threo -hex-2-enonic acid g-lactone, A-388 A-386 A-387 2-Acetamido-2,3-dideoxy-d-threo -hex-2-enono-1,5-lactone, A-389 2-Acetamido-1,2-dideoxy-d-arabino -hex-1-enopyranose, A-137 2-Acetamido-2,4-dideoxy-d-arabino -hexopyranose, A-391 2-Acetamido-2,4-dideoxy-d- yxo -hexopyranose, A-393 2-Acetamido-2,3-dideoxy-d-ribo -hexopyranose, A-395 2-Acetamido-2,4-dideoxy-d-ribo -hexopyranose, A-396...
A Nam
3S ,4S ,5R ,6S -form N-Ac Siastatin B. A 72363B. Antibiotic A 72363B 54795-58-3 C8H14N2O5 218.209 Isol. from Streptomyces verticillus var. quintum and Streptomyces nobilis. Potent neuraminidase inhibitor. Needles. Mp 137 dec. a D5 57.2 c, 1 in H2O . 3R ,4R ,5R ,6R -form N-Ac Antibiotic A 72363A1. A 72363A-1 C8H14N2O5 218.209 Prod. by Streptomyces nobilis. Hepar-anase inhibitor. Sol. H2O poorly sol. Me2CO, hexane. a D3 29 c, 1 in H2O . 3R ,4S ,5R ,6R -form N-Ac Antibiotic A 72363A2. A 72363A-2...
C Jeq
2-Feruloyl-1, 2'-disinapoylgentiobiose, G-410 1-Feruloyl-d-glucitol , G-247 Feruloylmalic acid, M-6 G-410 3'-Feruloyl-1 '-sinapoylsucrose , S-92 6-Feruloyl-3 -sinapoylsucrose, S-92 3'-O -Feruloyl-6-O -sinapoylsucrose, S-92 3'-Feruloylsucrose, S-92 6-O-Feruloylsucrose, S-92 Feruloyltartaric acid, T-12 Fetuin, F-3 3FG, D-89 FI 1163, L-52 FI 106, A-58 FIAC, F-4 Fiacitabine, F-4 Fialuridine, F-5 FIAU, F-5 Fibrase, X-3 Fibrezym, X-3 Finetose, M-15 Fischer-Baer ester, G-545 Flambabiose, F-7...
A A Fau
fairly sol. MeOH, C6H6, acids, Py, Me2CO, EtOH, dioxan poorly sol. Et2O, hexane, H2O. Mp 129-135 dec. a D4 29 c, 1 in CHCl3 . Log P 0.98 uncertain value calc . 1max 230 e 46900 258 e 26700 290 e 11400 434 e 13300 MeOH HCl Derep . 1max 240 e 55000 288 e 18800 314 e 12700 523 e 13800 MeOH NaOH Derep . 1max 230 e 43800 258 e 24400 290 e 10400 434 e 11900 MeOH Derep . 1max 228 E1 1cm 480 256 E1 1cm 260 292 E1 1cm 100 432 E1 1cm 130 MeOH Berdy . 1max 229 E1 1cm 540 258 E1 1cm 325 433 E1 1cm 160 EtOH...
CHNO Sxn
Modified nucleoside present in tRNAs. N6-Me 9- mt6A 39667-81-7 C16H22N6O8 426.385 Modified nucleoside present in tRNAs. Mp 159-160 . a D3 -5.3 c, 0.5 in H2O . 2- Methylthio ms2t6A 70333-82-3 C16H22N6O8S 458.451 Modified nucleoside present in tRNAs. Hong, C.I. et al., J. Med. Chem., 1971, 14, 748 1973, 16, 139 synth, uv, ir, pmr Dutta, S.P. et al., Biochemistry, 1975, 14, 3144 synth, Me deriv Kasai, H. et al., Eur. J. Biochem., 1976, 69, 435 uv, pmr, ms Parthasarathy, R. et al., Biochemistry,...
CHNO Xzh
Antibiotic. Cryst. Me2CO aq. . Mp 219-224 . a D' -54 c, 2 in dioxan . Log P 2.27 uncertain value calc . gt LD50 mus, orl gt 10000 mg kg. WM9800000 2 '- Ethyl carbonate 7218-80-6 C40H71NO15 805.999 Antibiotic. a D4 -75 c, 1 in CHCl3 . Log P 1.99 uncertain value calc . Cyclic 11,12-carbonate Davercin 55224-05-0 C38H65NO14 759.93 Antibiotic. Cryst. Me2CO aq. . Mp 219-224 . a D' -54 c, 2 in dioxan . Log P 0.92 uncertain value calc . KF4670000 N-De-Me N-Demethylerythromycin 992-62-1 C36H65NO13...
OH Mbd
Isol. from partial acid hydrolysates of Mp 176-180 . a D -11.8 c, 0.57 in H2O . Varshney, S.C. et al., J.C.S. Perkin 1, 1976, 1621 a-d-Glucopyranosyl- 102 - G-395 -d-glucopyranosyl- 1 03 -l-rham-nose a-d-Glucopyranosyl- 1 - gt 2 - -d-gluco-pyranosyl- 1 gt 3 -6-deoxy-l-mannose, 9CI - gt 6 - - G-394 4 -d-mannose, Me glycoside 130062-85-0 C19H34O15 502.469 Syrup. a D8 -10 c, 1.1 in CHCl3 . Me glycoside, nonabenzoyl 135129-58-7 C82H70O24 1439.441 Syrup. a D8 26.5 c, 1.65 in CHCl3 . Nifantev, P.E....
O Ibw
Me glycoside 130062-86-1 C19H34O15 502.469 Syrup. a D8 -70.9 c, 1.9 in CHCl3 . Me glycoside, nonabenzoyl 135129-57-6 C82H70O24 1439.441 Syrup. a D8 32.1 c, 1.0 in CHCl3 . Lipkind, G.M. et al., Can. J. Chem., 1990, 68, 1238 a-Me pyr, conformn, nmr Nifantev, P.E. et al., Bioorg. Khim., 1991, 17, 517 Sov. J. Bioorg. Chem. Engl. Transl. , 1991, 17, 292 a-Me pyr derivs -d-Mannopyranosyl- 1 4 - M-91 a-d-mannopyranosyl- 1 3 -l-rham-nose -d-Mannopyranosyl- 1 gt 4 -a.-d-manno-pyranosyl- 1 gt 3...
OH Owv
Me glycoside 130143-20-3 C19H34O13 470.47 Syrup. a D0 14.9 c, 1.0 in CHCl3 . Me glycoside, heptabenzoyl 135129-59-8 C68H62O20 1199.226 Syrup. a D8 -137 c, 1.0 in CHCl3 . Lipkind, G.M. et al., Can. J. Chem., 1990, 68, 1238 a-Me pyr, pmr, conformn Nifantev, P.E. et al., Bioorg. Khim., 1991, 17, 517 Sov. J. Bioorg Chem. Engl. Transl. , 1991, 17, 292 a-Me pyr heptabenzoyl, pmr, cmr 4-O -a-d-Fucopyranosyl-d-fu- F-112 cose
TriO methylenel
2,2,2-Trichloroethyl 3,6-di- O -benzyl-2-deoxy-2-ph.th.aHm.ido- -d- glucopyranoside, D-353 2,2,2-Trichloroethyl galactopyranoside, T-144 2,2,2-Trichloroethyl glucopyranoside, T-145 2,2,2-Trichloroethyl -d-glucopyranosiduronic acid, U-18 2,2,2-Trichloroethyl T-144 2,2,2-Trichloroethyl T-144 2,2,2-Trichloroethyl T-145 2,2,2-Trichloroethyl T-145 -benzoyl-a-d-galactopyranoside, T-144 1,2- O C-65 Trichlorogalactosucrose, S-91 chloride, F-96 chloride, F-96 3,4,6-Trichloro-3,4,6-trideoxyallose, T-146...
HO OH Pwh
C15H23N7O5 381.391 Nucleoside antibiotic. From Streptomyces griseolus and Streptomyces incarnatus. Antiviral agent with antifungal props. Never marketed. Log P -6.43 calc . 1max 207 15900 258 11100 H2O HCl Derep . 1max 256 14400 0.1N NaOH Derep . 1max 207 19800 258 12400 H2O Derep . gt LD50 mus, orl 1000 mg kg. HE3140000 S-Lactam Antibiotic RP 35391. RP 35391 67214-43-1 C15H21N7O4 363.375 From Streptomyces griseolus and Streptomyces incarnatus. Antifungal agent. - AU7356000 4,5-Didehydro...
OH Vkw
Syrup. a D0 -20 H2O . Erroneously drawn in the paper with the D-talo -config. Phenylosazone Fine yellow needles. Mp 178-179 dec. Erroneously called idoheptose phenylosazone. dehydrated in acid soln. to 2,7-anhydro deriv. 2,7-Anhydro d-Idoheptulosan 7575-38-4 C7H12O6 192.168 Cryst. EtOH . Mp 117-118 Mp 172-173 . a D0 -41 c, 1 in H2O . Pratt, J.W. et al., J.A.C.S., 1952, 74, 2210-2214 D-form, synth, -D-pyr-2,7-anhydro Kamal, A. et al., Pak. J. Sci. Res., 1971, 14, 63-67 68-70 a-L-pyr-form, isol,...
O Vsf
Helleborus foetidus. Needles EtOH aq. . Mp 206-208 . a D0 40.2 c, 0.5 in EtOH Tri-Ac Mp 175-176 . a D0 30 c, 1.0 in CHCl3 . Tschesche, R. et al., Chem. Ber., 1972, 105, 290 isol, pmr, ms Mariezcurrena, R.A. et al., Acta Cryst. B, 1973, 29, 1030 struct
Ho V Oh Oh 1
Note that the C atom carrying the OH which is cis to the COOH is normally numbered 3. Care is needed see Eliel 1997 . CA numbers the OH cis to the COOH, 5. Occurs in cinchona bark, coffee beans, tobacco leaves and many other plant sources. Food acidulant with good taste characteristics, use limited by cost. Sol. H2O. Mp 162-163 . a D -42.1 H2O . pKa 3.58 25 . - LD50 mus, scu 10000 mg kg. GU8650000 1,3-Lactone 9CI. Quinide. Quinolactone 665-27-0 C7H10O5 174.153 Constit. of Gardenia sootepensis...
Chchcooh 1
Pteridine nucleoside. Isol. from Pseudomonas ovalis. Useful as affinity chro-matog. ligand for purifn. of riboflavin. Inhibitor of Riboflavin synthase. Cryst. H2O . Mp 265 dec. Suzuki, A. et al., Bull. Chem. Soc Jpn., 1971, 44, 1869 isol Wrigglesworth, R. et al., CA, 1976, 84, 175673 Ginger, C.G. et al., J.C.S. Perkin 1, 1984, 953 959 synth, use Glycoprotein. Isol. from the carpophore of Psalliota xanthoderma. Shows antiviral activity. Sol. H2O. 1max 277 H2O Berdy . LD50 mus, ivn 318 mg kg....
CHO Bib
Cryst. EtOH . Mp 103-104 . a D -102 c, 1.6 in CHCl3 . Ferrier, R.J. et al., J.C.S., 1962, 3544 synth Burton, J.S. et al., J.C.S., 1965, 3433 synth Thanbichler, A. et al., Z. Naturforsch., B, 1971, 26, 912 synth Gutteridge, S. et al., Biochem. J., 1989, 260, 711 synth Beck, E. et al., Plant Physiol., 1989, 90, 13 pmr, cmr Moore, B.D. et al., Phytochemistry, 1993, 34, 703 occur Cryst. MeOH . Mp 110-111 . a D 7.7 -7 H2O . 4-Nitrophenylhydrazone Yellow needles EtOH . Mp 161-163 ....